I'll recall the definition of a Schubert variety X_w in a flag manifold G/B,
and the Bott-Samelson(-Demazure-Hansen) resolutions thereof.
In a precise sense, Schubert varieties cannot degenerate inside G/B.
So I will only degenerate affine patches on them, and prove the following:
1) Each patch degenerates to a union of coordinate spaces.
2) With respect to Bott-Samelson coordinates, the degeneration is controlled by a lexicographic Gr\"obner basis.
3) The combinatorics of the resulting Stanley-Reisner scheme is given by a "subword complex'', which is a shellable (even vertex-decomposable) ball.